https://forums.developer.apple.com/thread/76803
Try this, it fixed it for me. Open Terminal and run:
- cd ~
- mv .itmstransporter/ .old_itmstransporter/
- "/Applications/Xcode.app/Contents/Applications/Application Loader.app/Contents/itms/bin/iTMSTransporter"
iTMSTransporter will then update itself, then you can try uploading in XCode again.